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Operando modeling and measurements: Powerful tools for revealing the mechanism of alkali carbonate-based

《能源前沿(英文)》 2023年 第17卷 第3期   页码 380-389 doi: 10.1007/s11708-023-0872-x

摘要: Alkali carbonate-based sorbents (ACSs), including Na2CO3- and K2CO3-based sorbents, are promising for CO2 capture. However, the complex sorbent components and operation conditions lead to the versatile kinetics of CO2 sorption on these sorbents. This paper proposed that operando modeling and measurements are powerful tools to understand the mechanism of sorbents in real operating conditions, facilitating the sorbent development, reactor design, and operation parameter optimization. It reviewed the theoretical simulation achievements during the development of ACSs. It elucidated the findings obtained by utilizing density functional theory (DFT) calculations, ab initio molecular dynamics (AIMD) simulations, and classical molecular dynamics (CMD) simulations as well. The hygroscopicity of sorbent and the humidity of gas flow are crucial to shifting the carbonation reaction from the gas−solid mode to the gas−liquid mode, boosting the kinetics. Moreover, it briefly introduced a machine learning (ML) approach as a promising method to aid sorbent design. Furthermore, it demonstrated a conceptual compact operando measurement system in order to understand the behavior of ACSs in the real operation process. The proposed measurement system includes a micro fluidized-bed (MFB) reactor for kinetic analysis, a multi-camera sub-system for 3D particle movement tracking, and a combined Raman and IR sub-system for solid/gas components and temperature monitoring. It is believed that this system is useful to evaluate the real-time sorbent performance, validating the theoretical prediction and promoting the industrial scale-up of ACSs for CO2 capture.

关键词: CO2 capture     carbonation     theoretical modeling     operando techniques     reaction visualization    

Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 1837-1865 doi: 10.1007/s11705-023-2347-3

摘要: Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements and developments

关键词: Surface modification techniques    

Engineering

Raquel Portela, Susana Perez-Ferreras, Ana Serrano-Lotina, Miguel A. Bañares

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 509-536 doi: 10.1007/s11705-018-1740-9

摘要:

The term operando was coined at the beginning of this century to gather the growing efforts devoted to establish structure-activity relationships by simultaneously characterizing a catalyst performance and the relevant surface chemistry during genuine catalytic operation. This approach is now widespread and consolidated; it has become an increasingly complex but efficient junction where spectroscopy, materials science, catalysis and engineering meet. While for some characterization techniques kinetically relevant reactor cells with good resolution are recently developing, the knowledge gained with magnetic resonance and X-ray and vibrational spectroscopy studies is already huge and the scope of operando methodology with these techniques is recently expanding from studies with small amounts of powdered solids to more industrially relevant catalytic systems. Engineering catalysis implies larger physical domains, and thus all sort of gradients. Space- and time- resolved multi-technique characterization of both the solid and fluid phases involved in heterogeneous catalytic reactions (including temperature data) is key to map processes from different perspectives, which allows taking into account existing heterogeneities at different scales and facing up- and down-scaling for applications ranging from microstructured reactors to industrial-like macroreactors (operating with shaped catalytic bodies and/or in integral regime). This work reviews how operando methodology is evolving toward engineered reaction systems.

关键词: operando     structured catalysts     space-resolved     time-resolved     spectroscopy    

Application of endoscopic techniques in orbital blowout fractures

null

《医学前沿(英文)》 2013年 第7卷 第3期   页码 328-332 doi: 10.1007/s11684-013-0271-5

摘要:

Minimally invasive surgical techniques, particularly endoscopic techniques, have revolutionized otolaryngeal surgery. Endoscopic techniques have been gradually applied in orbital surgery through the sinus inferomedial to the orbit and the orbital subperiosteal space. Endoscopic techniques help surgeons observe fractures and soft tissue of the posterior orbit to precisely place implants and protect vital structures through accurate, safe, and minimally invasive approaches. We reviewed the development of endoscopic techniques, the composition of endoscopic systems for orbital surgery, and the problems and developmental prospects of endoscopic techniques for simple orbital wall fracture repair.

关键词: orbital fractures     endoscope     restoration     surgery    

Progress in studies of sex determination mechanisms and sex control techniques in

Qian ZHOU,Songlin CHEN

《农业科学与工程前沿(英文)》 2016年 第3卷 第2期   页码 113-123 doi: 10.15302/J-FASE-2016093

摘要: The (half-smooth tongue sole) is a marine flatfish of great commercial value for fisheries and aquaculture in China. It has a female heterogametic sex determination system (ZW/ZZ) and environmental factors can induce sex-reversal of females to phenotypic males, suggesting that it is a promising model for the study of sex determination mechanisms. Additionally, females grow much faster than males and it is feasible to improve the aquaculture production through sex control techniques. This paper reviews the progress in research on sex determination mechanisms research in our laboratory. We have completed whole-genome sequencing and revealed the genome organization and sex chromosome evolution of . A putative male determining gene was identified and DNA methylation was verified as having a crucial role in the sex reversal process. Genetic maps and sex-specific biomarkers have been used in a marker-assisted selection breeding program and for differentiation of the fish sex. Development and improvement of sex control technologies, including artificial gynogenesis and production of breeding fry with high proportion of females, is also reviewed. These research advances have provided insight into the regulation of sex determination and enabled efficient sex management in artificial culturing of .

关键词: Cynoglossus semilaevis     sex determination     sex control technique    

Artificial lift equipment repairing techniques in Daqing Oilfield

He LIU, Guochen SHI, Cui WANG, Peijing SHI, Yi XU,

《机械工程前沿(英文)》 2010年 第5卷 第1期   页码 111-117 doi: 10.1007/s11465-009-0081-2

摘要: To date, there are more than 60000 wells in Daqing Oilfield including injectors and producers. The annual investment is 1.07 billion RMB in the maintenance of artificial lift equipment, which is a heavy burden for the sustainable development of Daqing Oilfield. After years of study, a series of repairing techniques for artificial lift equipment have been created, which saved 0.5 billion RMB per year, leading to remarkable benefits and efficiency as well.This paper first presents the background of artificial lift equipment repairing technique in Daqing Oilfield. Then, a detailed introduction is given about the development history and current situation of key repairing technology, including the oil tube, rod string, and suck-rod pump. With reference to the study result in automobile and military territory remanufacturing technology, this paper analyzes the situation of artificial lift repairing techniques and evaluates the development direction and tendency of this field for a mature oilfield in the future.

关键词: artificial lift equipment     repairing technique     remanufacturing technique     Daqing Oilfield    

Assessment of popular techniques for co-processing municipal solid waste in Chinese cement kilns

《环境科学与工程前沿(英文)》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1485-4

摘要:

• Municipal solid waste (MSW) was fermented, screened, gasified, then co-processed.

关键词: Cement kiln     Co-processing     Environmental risk assessment     By-pass system    

Electromagnetic interference modeling and suppression techniques in variable-frequency drive systems

Le YANG, Shuo WANG, Jianghua FENG

《机械工程前沿(英文)》 2018年 第13卷 第3期   页码 329-353 doi: 10.1007/s11465-018-0466-1

摘要:

Electromagnetic interference (EMI) causes electromechanical damage to the motors and degrades the reliability of variable-frequency drive (VFD) systems. Unlike fundamental frequency components in motor drive systems, high-frequency EMI noise, coupled with the parasitic parameters of the trough system, are difficult to analyze and reduce. In this article, EMI modeling techniques for different function units in a VFD system, including induction motors, motor bearings, and rectifier-inverters, are reviewed and evaluated in terms of applied frequency range, model parameterization, and model accuracy. The EMI models for the motors are categorized based on modeling techniques and model topologies. Motor bearing and shaft models are also reviewed, and techniques that are used to eliminate bearing current are evaluated. Modeling techniques for conventional rectifier-inverter systems are also summarized. EMI noise suppression techniques, including passive filter, Wheatstone bridge balance, active filter, and optimized modulation, are reviewed and compared based on the VFD system models.

关键词: variable-frequency drive (VFD)     electromagnetic interference (EMI)     motor drive modeling     EMI noise suppression    

Acupuncture-related techniques for the treatment of opiate addiction: a case of translational medicine

Jisheng Han, Cailian Cui, Liuzhen Wu

《医学前沿(英文)》 2011年 第5卷 第2期   页码 141-150 doi: 10.1007/s11684-011-0136-8

摘要: Drug addiction is a chronic brain disorder characterized by withdrawal symptoms that occur during drug abstinence and a high tendency of relapse. Compared with the currently available pharmacological interventions, acupuncture therapy has the potential to help drug addicts stay away from drugs without major adverse side effects. It has taken decades of research to optimize the parameters of electrical acupoint stimulation for detoxification and for relapse prevention, as well as to establish a safe and easy procedure by which drug addicts can use it on themselves. The discovery that acupuncture can trigger the release of opioid substances from the brain in the 1970s provided the inspiration. Following this, basic research on animals made it possible to understand the mechanisms of action and establish the procedure for treating drug addictions. This article reviews the past, present, and foreseeable future regarding the use of acupuncture-related technique for the treatment of opiate addiction from the perspective of translational medicine.

关键词: morphine     dependence     withdrawal     addiction     dynorphins     acupuncture     electroacupuncture     transcutaneous electrical acupoint stimulation (TEAS)     enkephalins     endorphins    

A review of traditional and novel detection techniques for melamine and its analogues in foods and animal

Mengshi LIN,

《化学科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 427-435 doi: 10.1007/s11705-009-0244-z

摘要: Melamine, a nitrogen-rich chemical, has received much attention in recent years due to a series of highly publicized food safety incidents, including 2007 pet food recalls in North America and 2008 melamine contamination in milk, infant formula, and other milk-derived products in China. Current analytical methods for testing melamine are time-consuming, expensive, and labor-intensive. Therefore, there is an increasing interest in the food science and analytical chemistry field to develop simple, quick, sensitive, and cost-effective methods for detection of melamine and its analogues (e.g., cyanuric acid, melamine cyanurate, ammelide, and ammeline) in food ingredients, processed food, and animal feed. This review aims to summarize traditional and novel analytical techniques that have been used or show great potential to detect, characterize, and quantify melamine and its analogues in foods and animal feed.

关键词: milk-derived     Melamine     labor-intensive     cyanurate     time-consuming    

Cultivars and oil extraction techniques affect Cd/Pb contents and health risks in oil of rapeseed grown

《环境科学与工程前沿(英文)》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1687-z

摘要:

● Organic solvent extracted fewer Cd/Pb in rapeseed oil than physical pressing.

关键词: Rapeseed oil     Oil extraction technologies     Human health risk assessment     Cd/Pb-contaminated farmland     Substitute planting    

Novel sensing techniques for full-scale testing of civil structures

Kaoshan DAI, Zhenhua HUANG

《结构与土木工程前沿(英文)》 2012年 第6卷 第3期   页码 240-256 doi: 10.1007/s11709-012-0172-8

摘要: Performing full-scale structural testing is an important methodology for researchers and engineers in the civil engineering industry. Full scale testing helps the researchers understand civil infrastructures’ loading scenarios, behaviors, and health conditions. It helps the engineers verify, polish, and simplify the structural design and analysis theories. To conduct a full-scale structural testing, sensors are used for data acquisitions. To help structural researchers and engineers get familiar with sensing technologies and select the most effective sensors, this study reviewed and categorized new sensing techniques for full-scale structural testing applications. The researchers of this study categorized sensors used for civil-infrastructure testing into traditional contact sensors and remote sensors based upon their application methodologies, and into cabled sensors and wireless sensors based upon their data communication strategies. The detailed descriptions of wireless sensors and remote sensing techniques and their on-site full-scale applications are presented.

关键词: sensing technique     full-scale testing     wireless sensor     remote sensing     LiDAR     laser vibrometer    

Comprehensive review of modeling, structure, and integration techniques of smart buildings in the cyber-physical-social

《能源前沿(英文)》 2022年 第16卷 第1期   页码 74-94 doi: 10.1007/s11708-021-0792-6

摘要: Smart buildings have been proven to be a kind of flexible demand response resources in the power system. To maximize the utilization of the demand response resources, such as the heating, ventilating and air-conditioning (HVAC), the energy storage systems (ESSs), the plug-in electric vehicles (PEVs), and the photovoltaic systems (PVs), their controlling, operation and information communication technologies have been widely studied. Involving human behaviors and cyber space, a traditional power system evolves into a cyber-physical-social system (CPSS). Lots of new operation frameworks, controlling methods and potential resources integration techniques will be introduced. Conversely, these new techniques urge the reforming requirement of the techniques on the modeling, structure, and integration techniques of smart buildings. In this paper, a brief comprehensive survey of the modeling, controlling, and operation of smart buildings is provided. Besides, a novel CPSS-based smart building operation structure is proposed, and the integration techniques for the group of smart buildings are discussed. Moreover, available business models for aggregating the smart buildings are discussed. Furthermore, the required advanced technologies for well-developed smart buildings are outlined.

关键词: smart buildings     cyber-physical-social-system     optimization     modeling     demand response     virtual power plant    

Network-based optimization techniques for wind farm location decisions

Jorge Ignacio CISNEROS-SALDANA, Seyedmohammadhossein HOSSEINIAN, Sergiy BUTENKO

《工程管理前沿(英文)》 2018年 第5卷 第4期   页码 533-540 doi: 10.15302/J-FEM-2018025

摘要:

This study aims to find appropriate locations for wind farms that can maximize the overall energy output while controlling the effects of wind speed variability. High wind speeds are required to obtain the maximum possible power output of a wind farm. However, balancing the wind energy supplies over time by selecting diverse locations is necessary. These issues are addressed using network-based models. Hence, actual wind speed data are utilized to demonstrate the advantages of the proposed approach.

关键词: wind energy     wind farm location     network analysis     optimization     clique     s-plex    

Ensemble unit and AI techniques for prediction of rock strain

Pradeep T; Pijush SAMUI; Navid KARDANI; Panagiotis G ASTERIS

《结构与土木工程前沿(英文)》 2022年 第16卷 第7期   页码 858-870 doi: 10.1007/s11709-022-0831-3

摘要: The behavior of rock masses is influenced by a variety of forces, with measurement of stress and strain playing the most critical roles in assessing deformation. The laboratory test for determining strain at each location within rock samples is expensive and difficult but rock strain data are important for predicting failure of rock material. Many researchers employ AI technology in order to solve these difficulties. AI algorithms such as gradient boosting machine (GBM), support vector regression (SVR), random forest (RF), and group method of data handling (GMDH) are used to efficiently estimate the strain at every point within a rock sample. Additionally, the ensemble unit (EnU) may be utilized to evaluate rock strain. In this study, 3000 experimental data are used for the purpose of prediction. The obtained strain values are then evaluated using various statistical parameters and compared to each other using EnU. Ranking analysis, stress-strain curve, Young’s modulus, Poisson’s ratio, actual vs. predicted curve, error matrix and the Akaike’s information criterion (AIC) values are used for comparing models. The GBM model achieved 98.16% and 99.98% prediction accuracy (in terms of values of R2) in the longitudinal and lateral dimensions, respectively, during the testing phase. The GBM model, based on the experimental data, has the potential to be a new option for engineers to use when assessing rock strain.

关键词: prediction     strain     ensemble unit     rank analysis     error matrix    

标题 作者 时间 类型 操作

Operando modeling and measurements: Powerful tools for revealing the mechanism of alkali carbonate-based

期刊论文

Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements

期刊论文

Engineering

Raquel Portela, Susana Perez-Ferreras, Ana Serrano-Lotina, Miguel A. Bañares

期刊论文

Application of endoscopic techniques in orbital blowout fractures

null

期刊论文

Progress in studies of sex determination mechanisms and sex control techniques in

Qian ZHOU,Songlin CHEN

期刊论文

Artificial lift equipment repairing techniques in Daqing Oilfield

He LIU, Guochen SHI, Cui WANG, Peijing SHI, Yi XU,

期刊论文

Assessment of popular techniques for co-processing municipal solid waste in Chinese cement kilns

期刊论文

Electromagnetic interference modeling and suppression techniques in variable-frequency drive systems

Le YANG, Shuo WANG, Jianghua FENG

期刊论文

Acupuncture-related techniques for the treatment of opiate addiction: a case of translational medicine

Jisheng Han, Cailian Cui, Liuzhen Wu

期刊论文

A review of traditional and novel detection techniques for melamine and its analogues in foods and animal

Mengshi LIN,

期刊论文

Cultivars and oil extraction techniques affect Cd/Pb contents and health risks in oil of rapeseed grown

期刊论文

Novel sensing techniques for full-scale testing of civil structures

Kaoshan DAI, Zhenhua HUANG

期刊论文

Comprehensive review of modeling, structure, and integration techniques of smart buildings in the cyber-physical-social

期刊论文

Network-based optimization techniques for wind farm location decisions

Jorge Ignacio CISNEROS-SALDANA, Seyedmohammadhossein HOSSEINIAN, Sergiy BUTENKO

期刊论文

Ensemble unit and AI techniques for prediction of rock strain

Pradeep T; Pijush SAMUI; Navid KARDANI; Panagiotis G ASTERIS

期刊论文